1 Hydrocarbons
Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence of:
1) two ethylenic double bonds 2) an isopropyl group 3) a vinyl group 4) an acetylenic triple bond
SOLUTION
2 Biomolecules
Cynocobalamin contains which element
1) Co
2) Ca
3) Zn
4) Mg
3 Chemistry in Everyday Life
The carboxyl functional group (— COOH) is present in
1) picric acid 2) barbituric acid 3) ascorbic acid 4) aspirin
SOLUTIONS
4 Aldehydes Ketones and Carboxylic Acids
Acetone is soluable in water due to 1. methyl group 2. neutral nature 3. dissociation in water 4. hydrogen bonding
5 Titrations
For the reaction between KMnO4? and H2O2?, the number of electrons transferred per mole of H2?O2? is:
1) 1
2) 2
3) 3
4) 4
3H2?O2?+2KMnO4?−>3O2?+2MnO2?+2KOH+2H2?O
Number of electron transfer per mole ofH2O2? is 2.
6 Solutions
To what volume, in mL, must 50.0 mL of 3.50 M H2?SO4? be diluted in order to make 2 M H2?SO4??
1) 25 2) 60.1 3) 87.5 4) 93.2
No. of moles should be same in both cases so
M1?V1?=M2?V2?
or V2 ?= M1?V1?/M2? = 3.5×50/2 = 87.5ml
7 Hydrocarbons
The order of stability of the following carbocations:
1) III > II > I 2) II > III > I 3) I > II > III 4) III > I > II
8 Classification of Elements and Periodicity
The atoms/ion listed in correct order of increasing size are
1) Be2+, Mg2+, Na+
2) Na+, Cl -, K+
3) Al, Na, S
4) Na, Si, H
9 Chemical Equilibrium
One mole of hydrogen iodide is heated in a closed container of capacity 2 liters. At equilibrium half a mole of hydrogen iodide is dissociated. The equilibrium constant is 1) 1.00 2) 0.50 3) 0.25 4) 0.75
10 D and F Block Elements
Which is wrongly matched ?
1) Duralumin-Al+Cu+Mg+Mn 2) Alnico-Fe+Al+Ni+Co 3) German silver-Cu+Zn+Ni 4) Monel metal-Cu+Zn+Sn
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