1 Chemical Equilibrium
One mole of hydrogen iodide is heated in a closed container of capacity 2 liters. At equilibrium half a mole of hydrogen iodide is dissociated. The equilibrium constant is 1) 1.00 2) 0.50 3) 0.25 4) 0.75
SOLUTION
2 Biomolecules
Starting with three different amino acid molecules, how many different tripeptide molecules could be formed ?
1) 12 2) 9 3) 3 4) 6
3 Chemistry in Everyday Life
Which one of the following types of medicines is used for treating indigestion?
1) Antibiotic
2) Analgesic
3) Antacid
4) Antispetic
The indigestion is due to excess of acid produced in the stomach. The medicine used to neutralise it is called antacid
4 Chemical Equilibrium
The standard free energy changes for the reactions: 2H2(g) + O2(g) ? 2H2O(g) and CO(g) + H2O(g) ? CO2(g) + H2(g) are - 457.0 kJ and - 28.5 kJ respectively. Standard free energy for the reaction: 2CO2 ? 2 CO(g) + O2(g) will be: 1) – 514.0 kJ 2) – 485.4 kJ 3) 484.4 kJ 4) 514.0 kJ
On multiplying second eq. by 2 and adding to the first eqn.:
2CO(g) + O2(g) ? 2CO2(g) ΔG = - 457.0 + 2 × (- 28.5) = - 514.0 kJ Hence, for 2CO2(g) ? 2CO(g) + O2(g), ΔG = 514.0 kJ
The correct answer is: 514.0 kJ
5 Chemical Equilibrium
The equilibrium constant for the decomposition of water H2O(g) -> H2(g) + 1/2 O2(g) is given by : (α = degree of dissociation of H2O (g) ; p = Total equilibrium pressure )
6 Chemical Equilibrium
Kc for a gaseous state reversible reaction is 300 mol-2 L2 at 127oC. Hence, Kp of the reaction will be 1) 300 × (8.314 × 400)2 atm2 2) 300 × (8.314 × 127)2 atm2 3) 300 × (0.082 × 400)-2 atm-2 4) 300 × (0.082 × 300) atm
Kp = Kc(RT)Δn
Δn = -2 as shown by the units of Kc; R = 0.082 atm K-1 mol-1 Hence,Kp = 300 × (0.082 × 400)-2 atm-2
7 Organic Compounds Containing Nitrogen
In the reaction shown below, the major product(s) formed is/are
SOLUTIONS
8 Solid State
CsBr has b.c.c. structure with edge length 4.3 A. The shortest inter ionic distance in between Cs+ and Br– is:
1) 4.3 2) 1.86 3) 7.44. 4) 3.72
9 P – Block Elements
Which one of the following acid possesses oxidising, reducing and complex forming properties?
1) HNO3 2) HC1 3) H2SO4 4) HNO2
10 Hydrocarbons
The order of stability of the following carbocations:
1) III > II > I 2) II > III > I 3) I > II > III 4) III > I > II
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