1 Coordination Compounds
Among the ligands NH3, en, CN– and CO the correct order of their increasing field strength, is:
SOLUTION
2 Chemical Equilibrium
The expression for the solubility product of Ag2CO3 will be
1) Ksp = s2 2) Ksp = 4s3 3) Ksp = 27s4 4) Ksp = s
SOLUTIONS
3 Environmental Chemistry
Silk and woolen clothes are often damaged by
1) Flies
2) Insects
3) Bacteria
4) Animals
Because insects have the ability to digest silk and wool. Examples of insects that damage the clothes are-silverfish, cockroach, moth etc.
4 Electrochemistry
E0(Ni2+/Ni)=−0.25volt, E0(Au3+/Au)=1.50volt . The standard emf of the voltaic cell. Ni(s)|Ni2+(aq)(1.0M)|| Au3+(aq)(1.0M)|Au(s)Ni(s)|Ni(aq)2+(1.0M)||Au(aq)3+(1.0M)|Au(s) is: 1) 1.25 volt 2) - 1.75 volt 3) 1.75 volt 4) 4.0 volt
E0cell=(E0Ni/Ni2++E0Au3+/Au)
=(0.25+1.50)=1.75volt
5 Surface Chemistry
Which of the following forms cationic micelles above certain concentrations?
1) Sodium dodecyl sulphate 2) Urea 3) Sodium acetate 4) Cetyl trimethyl ammonium bromide
Sodium dodecyl sulphate and sodium acetate form anionic micelles due to larger size anions. Alkyl trimethyl ammonium ion aggregates to form a cationic micelle.
The reaction is as follows:
R(CH3)3NBr → R(CH3)3N+ + Br−
6 Surface Chemistry
A solution has positively charged colloidal particles. Which of the following solutions is required in lowest concentration for coagulation?
1) Na2SO4
2) ZnCl2
3) K4[Fe(CN]6
4) NaCl
7 Haloalkanes and Haloarenes
Fluorobenzene (C6H5F) can be synthesized in the laboratory
1) by direct fluorination of benzene with F2 gas 2) by reacting bromobenzene with NaF solution 3) by heating phenol with HF and KF 4) from aniline by diazotisation followed by heating the diazonium salt with HBF4
8 Practical Chemistry
A solution of a metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless solution. Moreover, the solution of metal ion on treatment with a solution of cobalt (II) thiocyanate gives rise to a deep blue crystalline precipitate. The metal ion is 1) Pb2+ 2) Hg2+ 3) Cu2+ 4) Co2+
9 D and F Block Elements
An aqueous solution containing Vx+ ion has magnetic moment equal to √ 15BM. Therefore, the x is:
1) 5 2) 4 3) 3 4) 2
Let n be the number of unpaired electrons. Magnetic moment = √ n(n+2) = √ 15
⇒n=3
Atomic number of Vanadium is 23. So, it must loose all its 4s electrons to get 3 unpaired d electrons.
∴value of x will be 2
10 P – Block Elements
Select the incorrect statement.
1) Cl2O6 is diamagnetic in solid state.
2) ClO3 is paramagnetic and exists in liquid state.
3) Cl2O6 is the anhydride of HClO3.
4) ClO3 for forms dimer due to unpaired electron.
Solution: Cl2O6 (di (dimer of ClO3) is mixed anhydride of HClO3 and HClO4.
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